A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.
Hi
I want to figure out how to calculate the temperature at which more energy is required to keep hydrogen and oxygen together (as in the case of H2O) than to separate them...in other words the temperature at which hydrogen and oxygen will no longer combine due to extreme temperatures. How...
How do electrons revolve around in molecule bonded by covalent bonds? An electron revolves around one nucleus. But if it is going to be shared by another nucleus(as in covalent bond), then how will the electron revolve? does it go all around both the nucleus? Please explain a little deeply.
I would like some help with the following problems
1. Consider in R^{j}={f : f = \Sigma^{l}_{m=-l} a^{m}f^{l}_{m}} the operator \stackrel{\rightarrow}{e}\bullet\stackrel{\rightarrow}{J}, where \stackrel{\rightarrow}{e} is a unit vector in 3-dimensional space.
(a) Calculate the probabilities...
As we know, plastic is non-conductor, iron metal is conductor, does anyone have any suggestions on what kind of property in term of molecule structure allows electricity to get through?
Thanks in advance for any suggestions
Homework Statement
Hello, this is not actually a homework problem. I just can't seem to understand the derivation of the average translational kinetic energy of a molecule. I am startled by the way the velocities are added.
Homework Equations
My undergraduate level textbook says...
I am Looking for a green color molecule less than 3 angstrom in size...
I have found Cr2O3 but its greater than 3.5 angstrom... so anything smaller will do the job :)
Thanks in advance.
Is there any systematic, predictive way to calculate the resonance frequency of a given molecule?
Say I'm given a formula and a structure but nothing else. Is there any way to calculate it without just experimenting?
I'm not sure if this question is in the right place, and I'm not...
Hello,
I was confused about which bond is stronger, ionic or covalent... thinking and searching about that, I found (or better, realized) that when we talk about the boiling point of water, its just that it's INTERMOLECULAR forces get weaker, not the covalent bond present between the ATOMS ...
Hi all, I consider a square planar molecule such as XeF4, Xe atom is at the center, F atoms are at the corners of a square. In the character table of D4h group that XeF4 belongs to, I see that there are two C4 axes but I only can find one that goes through the Xe atom and is perpendicular to the...
Hi,
Homework Statement
I am trying to determine the size of a molecule..by doing the oil drop experiment where we drop a tiny droplet of oil on water covered with a thin layer of powder...and then make calculations based on the diameter of the circle... the droplet forms in oil.
The Attempt...
Suppose two particles or molecules are generated (produced) together. If one molecule is taken away from the another, let us say to another city. If we make some certain changes in anyone of them, e.g if we change its motion if it was in clock wise and we change it to anti-clock wise. So by...
When calculating the kinetic energy of a rotating water molecule (translational and vibrational motion not important here), am I correct in assuming that you do all the calculations from the center of mass and analyze each axis of rotation (x,y,z)? The bent geometry is throwing me off! Any...
When calculating the kinetic energy of a rotating water molecule (translational and vibrational motion not important here), am I correct in assuming that you do all the calculations from the center of mass and analyze each axis of rotation (x,y,z)? The bent geometry is throwing me off! Any...
Any idea that this molecule is?
Fig.A shows the molecule and the electron orbitals and bonds.
Fig.B is the same image with very approximate bond angles and molecular geometry angles. All the angles are close approximations.
The angles are written in black and the number of electrons are in...
i need help to find :
1) a surface area and volume of a c60 molecule. Assume the structure is a truncated icosahedron (Faces=32, Edges=90 and Vertices=60). The mean c60 diameter is 0.68nm but Van der Waals diameter is closer to 1nm.
2) electronic properties of c60 molecule, like how many...
Homework Statement
Calculate the ratio of frequencies of oscillations of the molecules H2 and HD.
Homework Equations
f=(1/2pi)(k/m)^0.5
f=frequency
k=spring constant
m= mass or reduced mass
The Attempt at a Solution
I got (2/6)^0.5 but the given answer is (4/3)^0.5.
I...
Homework Statement
Two identical atoms in a diatomic molecule vibrate as harmonic oscillators. However, their center of mass, midway between them, remains at rest.
1)Show that at any instant, the momenta of the atoms relative to the center of mass are p and -p
2)Show that the total...
Homework Statement
I have to sketch a phase portrait (in phase space) for a system which is a diatomic molecule. The effective potential is equal to a potential that is attractive at long range and repulsive at short range plus the centrifugal barrier. It basically looks like a Morse...
The question is: Which substance has the highest melting point?
(A) CO (B) CO2 (C) SiO2 (D) P2O5
The answer is C but I don't know why (you obviously can't look up the values). I need to be able to figure these types of questions out regardless of the...
hi,
i need to explain how molecules of ethene combine together to form a poly(ethene) molecule?
would it be because the double bond is broken and 2 bonds them placed on the outside of the Carbons (C)?
if this is not correct could someone please let me know where I am going wrong!
thanks!
Homework Statement
Name the following (organic) molecule:
http://img827.imageshack.us/img827/1883/organicmolecule.png
Uploaded with ImageShack.usHomework Equations
The Attempt at a Solution
Would this be 3-pentene? The root has to be "pent" because that's the longest carbon chain, right?
Hi there!
I'm studying the hydrogen molecule. According to the MO technique I start from one-electron molecular orbitals to construct the wave function of the entire molecule.
Afa hydrogen is concerned, I can construct two ^1\Sigma_g orbitals:
\Phi_A=\Phi_g(1)\Phi_g(2)\chi_{0,0}...
Homework Statement
Using specific heat data for a nitrogen molecule, estimate then vibrational frequency of the diatomic molecule
Homework Equations
C= 3N_a k = 3R
The Attempt at a Solution
unable to attempt a solution
Does anyone tell me why the potential energy increase(becomes more positive) when two atom put closer to each other which is smaller than the equilibrium bond distance while potential energy decrease(becomes more negative) when two atoms put closer to each other (which is close to equilibrium...
Hi everyone,
I'm wondering if its possible to design a molecule that re-arrange on an electromagnetic (non-visible and radio) signal, and revert back to original structure when signal stops.
Thanks in advance
I have a planar molecule with a torsional oscillation mode where it twists around a C-C bond by an angle \theta from some equilibrium position.
The restoring force is a function of theta, and the potential energy involved is given by V(\theta) = V_0(1-cos(2\theta))
I need to "use a Taylor...
Ok I can see the 5 end is negative, is the 3 end positive due to OH. So in other strand this goes other way round. Is this what they mean when they say there is reverse polarity in a DNA molecule. Thanks!
The energies of the ground and third level of a certain molecule are 1.15 x 10-20 J and 4.31 x 10-20 J respectively.
What is the frequency (in Hz) of the photon emitted when this molecule drops from the third vibrational level to the ground level?
You don't have to solve it. Could someone...
Hi,
If the normalized 1D wave-function of hydrogen atom for n=1, l=0, m_l=0;
\psi_{1s}(x)=\frac{1}{\sqrt{\pi} a_{0}^{3/2}}e^{-x/a_{0}}
and probability distribution of wave-function,
\mid\psi_{1s}(x)^2\mid
so integration of rho over all x should give the number of electrons which is equal to...
Hi,
I consider harmonic model of diatomic molecule: two atoms connected with a massless rod. Let one axis be along the rod, other two perpendicular to it. Let rotational velocity have components only trough perpendicular axes. In one book it is said that rotational energy of such diatomic...
Look for yourself. If a member posted one of these, he'd probably get an infraction. Cummingtonite, ok it's a mineral.
http://www.chm.bris.ac.uk/sillymolecules/sillymols.htm
Homework Statement
Hi guys
I know the molar mass (i.e. g/mole) of H and O, but from this, then how do I find the volume of 1 water molecule? I know the densities of H and O as well, from which I can find the volume of H and O. Do I just add these, one of V_oxygen and two of V_hydrogen (I...
Homework Statement
The potential energy V between the two hydrogen atoms ( mH = 1.672*10^(-24) g) in a
hydrogen molecule is given by the empirical expression V = V0 [ exp(-2a(r-r0)) - 2exp(-a(r-r0))] where
V0 = 7*10^(-12) erg, a = 2*10^8 cm-1, r0 = 8*10^-9 cm.
(a) Estimate the...
Homework Statement
The energy of a rotator ( a dumbbell-shaped object) is given by L^2/2I, where L is the angular momentum and I is the rotational inertia (moment of inertia) of the dumbbell. Consider an HCl molecule, in which the atomic weights of H and Cl are 1 and 35, respectively, and...
Homework Statement
Okay here's the problem, normally I can get all this stuff, but right now this is blowing my mind, partly because its too general.
"In other problems and examples in the textbook we found the effective spring stiffness corresponding to the interatomic force for aluminum...
How can I calculate the attractive electric force between the unlike atoms of a water molecule?
Would I use Coulomb's law?
Using Coulomb's law: I don't understand the radius I would use?
I know that the selection rule is :
\DeltaJ = +/- 1
but our prof said that according to some quantum mechanical calculations the odd values of J are not allowed. So, the allowed transitions are :
J 0 <-> 1 ; 2 <-> 3 ; 4 <-> 5... as...
Homework Statement
Spectroscopic data (rotational-vibrational lines) show that the hydrogen fluoride molecule has a vibrational frequency of 7.8x10^14 rad/sec and a moment of inertia of I=1.35x10^-47 kg.m^2. Find the relevant characteristic temperatures of the HF molecule.
Homework...
I've studied a little organic chemistry but I couldn't figure it out. I've never seen it before but I'm sure it's simple to name, yet I couldn't find anything on Google.
I'm not a science student. So, please keep your reply simple and straightforward. Thank you.
A fat molecule is made up of two types of molecules: glycerol and fatty acid. There are different kinds of fatty acids. Are there also different types of glyceol, does it come only in one variety...
Homework Statement
a) Find the probability that a molecule will travel a distance at least equal to the mean free path before its next collision.
b)After what distance of travel since the last collision is the probability of having suffered the next collision equal to 1/2?
Homework...
Homework Statement
Value of the Van der walls constant for the oxygen is 32 cubic centimeter. Find the diameter of the oxygen molecule?
Homework Equations
thermodynamics problem
The Attempt at a Solution
Homework Statement
I have been wondering about temperature and it's relation to kinetic energy I didn't study thermodynamics so I hope that replies could be simplified.I am trying to think about the perfect gas law to relate kinetic energy per molecule to temperature, and I want to know if I...
Homework Statement
From the average separation between air molecules at STP, and their mean speed, estimate how long it would take one molecule to move into the region occupied by another. Assume that air consists mainly of nitrogen molecules.
Homework Equations
1/2mv^2 = 3/2KT...
Hi,
I'm doing some calculations on fluorescence and I'm a little stuck on statistics.
Let's say I need to measure 20 seconds to collect 10000 photons from a single molecule.
Then I can say well I want to measure at most 1 second and therefore I need 20 molecules in order to collect 10000...
Homework Statement
A polarized water molecule is near a long charged wire and experiences a force due to the charge. How do you determine the net force on this molecule assuming the molecule is perpendicular to the center of the rod and nothing polarizes further.
The Attempt at a Solution...
You can obtain a rough estimate of the size of a molecule with the following simple experiment: Let a droplet of oil spread out on a fairly large but smooth water surface. The resulting ”oil slick” that forms on the surface of the water will be approximately one molecule
thick.
Given an oil...
The Hamiltonian of the diatomic molecule is given by H = p1^2 / 2m + p2^2 / 2m + 1/2 k R^2, where R equals the distance between atoms. Using this result, given in standard texbooks, I keep geting C = 9/2 kT instead of 7/2 kT for heat capacity. I've traced down my problem to the potential energy...