- #3,396
Astronuc
Staff Emeritus
Science Advisor
2023 Award
- 22,185
- 6,854
Here is another good overview of the Fukushima event.
www.vgb.org/vgbmultimedia/News/Fukushimav15VGB.pdf
Regarding the chemistry - it's complicated. The introduction of seawater into a core of stainless steel (SS304) and Zircaloy-2 complicates an already complicated situation. Radiolysis is a factor not normally considered in chemistry. One the fuel breaches it becomes even more complicated.
The Zr-liner on the inside of the cladding will react readily with steam. Zr-2 is normally resistant to corrosion, but high temperatures reduce the corrosion resistance, and the presence of ferric chloride also significant reduces corrosion resistance of Zr-2.
Some reactor accident analyses indicate the presence of I2. Iodine is a fission product in the fuel, as is cesium. If elemental iodine can be formed, then possibly elemental Cl2 could also form from similar reactions. On the other hand, chlorine is very reactive. Should the Cl2 react with steam, Zr-2, or stainless steel, or any of the metal oxides? If the core is dry (in steam, without water), what is the environment in the steam? Hydrogen is certainly generated because we now that significant hydrogent was generated at Units 1 and 3, and that hydrogen subsequently detonated.
www.vgb.org/vgbmultimedia/News/Fukushimav15VGB.pdf
Regarding the chemistry - it's complicated. The introduction of seawater into a core of stainless steel (SS304) and Zircaloy-2 complicates an already complicated situation. Radiolysis is a factor not normally considered in chemistry. One the fuel breaches it becomes even more complicated.
The Zr-liner on the inside of the cladding will react readily with steam. Zr-2 is normally resistant to corrosion, but high temperatures reduce the corrosion resistance, and the presence of ferric chloride also significant reduces corrosion resistance of Zr-2.
Some reactor accident analyses indicate the presence of I2. Iodine is a fission product in the fuel, as is cesium. If elemental iodine can be formed, then possibly elemental Cl2 could also form from similar reactions. On the other hand, chlorine is very reactive. Should the Cl2 react with steam, Zr-2, or stainless steel, or any of the metal oxides? If the core is dry (in steam, without water), what is the environment in the steam? Hydrogen is certainly generated because we now that significant hydrogent was generated at Units 1 and 3, and that hydrogen subsequently detonated.