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Yes, photon number is determined by any eigenstate of the number operator.vanhees71 said:This means that a one-photon and a two-photon state are always orthogonal and thus well distinguishable. It's not clear to me what this has to do with coherence or incoherence.
But the question was different, namely how to distinguish whether one should regard a given (pure or mixed) 2-photon state (thus containing exactly 2 photons) as a single quantum object or as two separate objects.